Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Rapid Communications
Non-destructive Rapid Analysis Discriminating between Chromium(VI) and Chromium(III) Oxides in Electrical and Electronic Equipment Using Raman Spectroscopy
Sonoko KIKUCHIKazuteru KAWAUCHIMasaru KUROSAWAHisashi HONJHOTeruo YAGISHITA
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2005 Volume 21 Issue 3 Pages 197-198

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Abstract

The European Union has banned chromium(VI) compounds in electrical and electronic equipment (EEE), such as chromate conversion coating films. Chromium(III) compounds are not banned. Using Raman spectroscopy without any preparation, we distinguished chromium(VI) oxide from chromium(III) oxide and chromium(III) hydroxide in chromate conversion coating films. Raman bands of chromium(VI) oxide were detected in films at around 1000 and 500 cm-1, while chromium(III) compounds generated no bands in the region between 2000 and 200 cm-1. The analysis took about 1 min, whereas the usual diphenylcarbazide-colorimetric method for analyzing chromium(VI) compounds takes about 10 h.

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© 2005 by The Japan Society for Analytical Chemistry
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