e-Journal of Surface Science and Nanotechnology
Online ISSN : 1348-0391
ISSN-L : 1348-0391
Regular Papers
A quantum dynamics study on the H+ transmission in a Pt-Nafion interface
Nelson B. Arboleda Jr.Muneyuki TsudaHideaki Kasai
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2006 Volume 4 Pages 640-643

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Abstract

We performed a quantum dynamics study on the proton-like hydrogen (H+) transmission from the platinum (Pt) electrode to the Nafion side chain. In particular, we calculated the transmission probability (Tp) for H+ from the Pt side to the Nafion side using the coupled-channel method via the local reflection (LORE) matrix scheme and plotted Tp as a function of the H+ initial translational energy. Our results showed that without quantum effects, H+ transmission across the Pt-Nafion interface will be impossible to proceed at the operating temperatures (i.e. 353-373 K) of conventional fuel cells. We also found that the asymmetric nature of the barrier in the system we considered enhances the transmission. [DOI: 10.1380/ejssnt.2006.640]

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この記事はクリエイティブ・コモンズ [表示 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by/4.0/deed.ja
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