Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
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石英管封入法による高温超伝導体 Hg0.8M0.2Ba2Ca2Cu3Oy (M=V, Cr, Mn, Mo, Ag, In, Sn, W, Re, Pb, Hf, Ta)の合成
安達 成司菅野 剛森脇 義幸田辺 圭一
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2005 年 113 巻 1322 号 p. 678-683

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Samples with nominal compositions of Hg0.8M0.2Ba2Ca2Cu3Oy (M=V, Cr, Mn, Mo, Ag, In, Sn, W, Re, Pb, Hf, Ta) were prepared by a conventional quartz-tube encapsulation method at ambient pressure. The 1223 phase formed in the samples with dopants except In and W. Ag, Re and Pb-doping effectively expanded the temperature range for formation reaction of the 1223 phase. For samples with V, Cr, Mn, Mo and Re, appreciable shortening in the lattice parameter c was observed. It suggested incorporation of the dopants into the 1223 phase. Magnetization measurements at 77 K revealed that an enhancement in the critical current density was achieved in the samples with Re and Mo.

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© 2005 The Ceramic Society of Japan
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