Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Nanostructure control of liquid-phase sintered Si3N4 ceramics by spark plasma sintering
Mikinori HOTTAJunichi HOJO
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2009 Volume 117 Issue 1372 Pages 1302-1305

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Abstract

Submicron-sized α-Si3N4 and nanosized amorphous Si3N4 powders were sintered by spark plasma sintering at 1700°C for holding times of 60 to 120 s at heating rates of 1.7 to 6.1°C/s with Y2O3 and Al2O3 sintering additives. The nanostructure control of liquid-phase sintered Si3N4 ceramics was achieved by selecting optimum heating schedules such as temperature, holding time and heating rate. Fully dense nanostructured β-Si3N4 ceramics with grain size of 150 nm were prepared using nanosized amorphous Si3N4 starting powder. The transformation to β-phase in Si3N4 ceramics obtained from the nanosized amorphous Si3N4 powder was more greatly accelerated than that from submicron-sized α-Si3N4 powder.

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© 2009 The Ceramic Society of Japan
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