Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
Technical reports
Effect of reactant C/Ti ratio on the stoichiometry of Combustion-synthesized TiCx in Ti-C system
Binglin ZOUShenbao JINPing SHENQichuan JIANG
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2009 Volume 117 Issue 1364 Pages 525-528

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Abstract

In this study, self-propagating high-temperature synthesis (SHS) of the powder compact consisting of titanium and graphite was used to synthesize titanium carbide (TiCx). The relationship between the C/Ti ratio in the reactants and the stoichiometry of the resultant TiCx phase was investigated. The result showed that when the molar ratio of C to Ti in the reactants increased from 0.6 to 1.2, the stoichiometry of the resultant TiCx phase first increased and then decreased with the maximum value appearing at C/Ti = 1.0, so did the change in the maximum combustion temperature; Furthermore, with an increase in the particle size of graphite, the maximum combustion temperature and the stoichiometry of the resultant TiCx phase decreased. Consequently, the maximum combustion temperature might play a dominating role in determining the final composition of the TiCx phase.

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© 2009 The Ceramic Society of Japan
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