表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
論文
フタロシアニン1次元πスタック構造の観察
内藤 泰久松本 卓也杉浦 健一坂田 祥光川合 知二
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2000 年 21 巻 8 号 p. 496-501

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Monolayers or submonolayers of zincphthalocyanine (ZnPc) deposited on highly oriented pyrolytic graphite (HOPG) substrates have been investigated by scanning tunneling microscopy (STM). Structures of ZnPc layers show characteristic low dimensional structures. When the ZnPc coverage is under 1 ML, twined stripestructures with three-fold symmetry were observed. This structure can be explained in terms of a commensurate superstructure of unit cell β form crystalline on the HOPG. When the ZnPc coverage is over 1 ML, one-dimensional structures like a wire were observed. The width and length of the wire are 6 nm and longer than 1 μm, respectively. These structures would also originate from the π-staking of ZnPc molecules.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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