表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
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谷 俊彦
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ジャーナル フリー

2001 年 22 巻 11 号 p. 753-760

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We developed a novel processing method, the reactive templated grain growth (RTGG), for the fabrication of highly textured polycrystalline ceramics with a regular perovskite-type structure. Plate-like particles with a layered perovskite-type structure were used as a reactive template, of which the preferred orientation was preserved in the in-situ formed regular perovskite-type polycrystals after heat-treatment. The textured ceramics exhibited a brick-wall-like microstructure and enhanced piezoelectric properties. The mechanism of conversion from a layered perovskite-type template into a regular perovskite-type product was rather topotactic. Furthermore, the RTGG processing was also applied to the fabrication of more complex bismuth layer-structured (BLS) ceramics with a preferred {001} orientation. The textured BLS ceramics exhibited 3–4 times as high piezoelectric coefficients and electromechanical coupling factors as the conventionally sintered BLS ceramics of the same compositions. The textured BLS ceramics showed a layered-slate-like microstructure. The unique microstructures of the two types of textured ceramics ({100}-oriented regular perovskite and {001}-oriented BLS) reflected anisotropy in terms of the surface energy for the crystal structures of regular perovskite and BLS.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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