表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
特集:非接触原子間力顕微鏡—なにがどこまで見えるか?—
非接触原子間力顕微鏡によるTiO2(110)及びCeO2(111)表面上での原子・分子の動的挙動の観察
福井 賢一岩澤 康裕
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2002 年 23 巻 3 号 p. 141-148

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Our recent studies on metal oxide surfaces by noncontact atomic force microscopy (NC-AFM) are reviewed. We have demonstrated that atom-resolved images of a TiO2(110) surface can be obtained by NC-AFM. We have also revealed that isolated species of formate ions and hydrogen adatoms on TiO2(110) can be imaged by NC-AFM. As an example of observation of dynamic behavior of adsorbed molecules by NC-AFM, images of fluctuating molecules of acetate ions at domain boudaries of (2×1)-acetate overlayer on TiO2(110) are presented. CeO2−x has been believed to play a crucial role in automotive exhaust catalysis with its special oxygen storage capacity. Surface oxygen atoms at an oxygen-terminated CeO2(111) surface, oxygen point vacancies, and multiple oxygen vacancies such as triangular defects and line defects were visualized by NC-AFM. Unexpected high mobility of surface oxygen atoms at room temperature was observed on slightly reduced CeO2(111) with multiple defects. This observation is probably relevant to facile oxidation-reduction cycles of CeO2−x.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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