A precise surface design of particle, based on the quantitative evaluation between micro physical and macro physical properties on particle surface, is paid to attention in the background of the demand of preparing the high performance material in recent year. In this paper, the knowledge and the method for preparing the particle surface which had aimed physical properties were reviewed. The basic knowledge concerning a real particle surface was introduced at first. Some cases of preparing the functional particle surface by a precise surface design were shown. The positive use of the particle surface such as photo catalysis was also introduced.