表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
特集:散逸的構造形成
電極表面反応における振動現象と時空間パターン形成
中西 周次
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ジャーナル フリー

2007 年 28 巻 11 号 p. 642-646

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Formations of spatiotemporal patterns in nonlinear chemical reactions have attracted a lot of attentions from the viewpoint of dynamic self-organization in molecular systems. It is now widely known that such spatiotemporal patterns can also be observed in electrochemical systems. The electrochemical system has advantages for the study of the dynamic spatiotemporal patterns: (1) the distance from the equilibrium can be tuned continuously and reversibly by simply changing the electrode potential, (2) the diffusion processes can be flexibly controlled by tuning the structure of the electrochemical cell, and (3) the mode of the spatiotemporal patterns can be tuned easily by changing the geometrical arrangements of the electrodes and the applied potential or current. Here we review experimental and theoretical studies on the spatiotemporal patterns formed at electrode surfaces, by taking electrochemical oscillation during H2O2 reduction on Pt electrode as a representative example.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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