表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
特集:散逸的構造形成
自励振動ゲルを用いた時空間機能表面の作製
酒井 崇匡吉田 亮
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2007 年 28 巻 11 号 p. 647-652

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Stimuli-responsive polymers and their applications to sensors and actuators are widely studied. On the other hand, we have prepared the novel self-oscillating polymer and gels by utilizing the chemical energy of Belousov-Zhabotinsky (BZ) reaction. The polymer is composed of poly (N-isopropylacrylamide) in which Ru (bpy)3, a catalyst for the Belousov-Zhabotinsky (BZ) reaction, is covalently bonded to the polymer chain. Under the coexistence of the reactants (malonic acid, sodium bromate and nitric acid), the polymer undergoes spontaneous cyclic soluble-insoluble changes or swelling-deswelling changes (in the case of gel) without any on-off switching of external stimuli. In this review, the design of self-motive nano-conveyer by arraying the micro-gel beads on surface and novel fabrication method —double template polymerizaiton— were summarized.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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