BIOCHEMICAL STUDIES ON 2-DEOXY-SCYLLO-INOSOSE, AN EARLY INTERMEDIATE IN THE BIOSYNTHESIS OF 2-DEOXYSTREPTAMINE I. CHEMICAL SYNTHESIS OF 2-DEOXY-SCFLLO-INOSOSE AND [2, 2-2H2]-2-DEOXY-SCYLLO-INOSOSE

NORIAKI YAMAUCHI; KATSUMI KAKINUMA

doi:10.7164/antibiotics.45.756

The Journal of Antibiotics

Online ISSN : 1881-1469
Print ISSN : 0021-8820
ISSN-L : 0021-8820

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Volume 45 (1992) Issue 5
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BIOCHEMICAL STUDIES ON 2-DEOXY-SCYLLO-INOSOSE, AN EARLY INTERMEDIATE IN THE BIOSYNTHESIS OF 2-DEOXYSTREPTAMINE

I. CHEMICAL SYNTHESIS OF 2-DEOXY-SCFLLO-INOSOSE AND [2, 2-²H₂]-2-DEOXY-SCYLLO-INOSOSE

NORIAKI YAMAUCHI, KATSUMI KAKINUMA

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JOURNAL FREE ACCESS

1992 Volume 45 Issue 5 Pages 756-766

DOI https://doi.org/10.7164/antibiotics.45.756

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Abstract

A practical preparative method for 2-deoxy-scyllo-inosose, the earliest key intermediate leading to 2-deoxystreptamine, was devised as a prerequisite to more detailed biochemical studies on the biosynthesis of 2-deoxystreptamine. [2, 2-²H₂]-2-Deoxy-scyllo-inosose was also synthesized through a modified Ferrier reaction.

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