粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
ホウ酸の微量添加によるフェライト磁性材料の低温作製とその特性評価
辺 培巨 東英三田村 孝
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2003 年 50 巻 9 号 p. 721-725

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Recently, magnetite (Fe3O4) of ferrite magnetic materials has attracted attentions arising from the scientific inter-est in clarifying material properties and its potential applications. However, its industrial applications have been limited by the need of high temperature (ca. 1500°C) sintering under reduced pressure or vacuum. So the purpose of this study is to fabricate the magnetite sintered body with high-strength and soft magnetism at relatively mild condi-tions. The manufacturing procedures are as follows: fine magnetite powder was synthesized under a CO2 atmo-sphere at 500°C from the oxalic acid iron by liquid phase sedimentation using iron chloride and ammonium oxalate; subsequently, a small amount of boric acid [H3BO3] was added to the powder, and then the magnetite powder com-pact was prepared with Newton press and CIP methods. Finally, the Fe3O4 sintered body was fabricated by sintering at 1050°C under a CO2 atmosphere which is lower in comparison with the traditional manner. By this method, we obtained magnetite sintered body with 0.5 mass% boric acid additive being of high strength (400 MPa), high satura-tion magnetization value and low coercive force.

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