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Investigation of Adsorbed Ethylene on Pt(111) Using a Small IRAS Cell
Toshiaki OHTANI, Jun KUBOTA, Junko NOMURA, Chiaki HIROSE, Kazunari DOMEN
Author information
-
Toshiaki OHTANI
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
-
Jun KUBOTA
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Junko NOMURA
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Chiaki HIROSE
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Kazunari DOMEN
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
JOURNAL
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1997 Volume 18 Issue 7 Pages 441-446
Details
- Published: July 10, 1997 Received: February 20, 1997 Available on J-STAGE: August 07, 2009 Accepted: - Advance online publication: - Revised: -
-
Correction information
Date of correction: August 07, 2009 Reason for correction: - Correction: ABSTRACT Details: Wrong : Adsorption of ethylene on bare and ethylidyne-covered Pt(111) surfaces in the presence of gaseous ethylene was investigated using infrared reflection absorption spectroscopy (IRAS). An IRAS peak at 954 cm-1 from ethylene was reversibly adsorbed on the bare Pt(111) at 10 Ton and 150∼180 K which was assigned to the C-H out-of-plane bending mode of n bonded ethylene. The heat of adsorption of π-bonded ethylene on Pt(111) was estimated to be 35±10 kJ/mol from the analysis of the adsorption isobar. On the ethylidyne-covered Pt(111), reversibly adsorbed π-bonded ethylene was also observed under the same condition where an IRAS peak at 954 cm-1 appeared. The adsorption of π-bonded ethylene on ethylidyne-covered Pt(111) was weaker than that on the bare Pt(111).
Right : Adsorption of ethylene on bare and ethylidyne-covered Pt(111) surfaces in the presence of gaseous ethylene was investigated using infrared reflection absorption spectroscopy (IRAS). An IRAS peak at 954 cm-1 from ethylene was reversibly adsorbed on the bare Pt(111) at 10 Ton and 150∼180 K which was assigned to the C-H out-of-plane bending mode of n bonded ethylene. The heat of adsorption of π-bonded ethylene on Pt(111) was estimated to be 35±10 kJ/mol from the analysis of the adsorption isobar. On the ethylidyne-covered Pt(111), reversibly adsorbed π-bonded ethylene was also observed under the same condition where an IRAS peak at 954 cm-1 appeared. The adsorption of π-bonded ethylene on ethylidyne-covered Pt(111) was weaker than that on the bare Pt(111).
Date of correction: August 07, 2009 Reason for correction: - Correction: CITATION Details: Wrong : 1) J.C. Bertolini and J. Massardier: “The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis”, ed. by D.A. King and D.P. Woodruff (Elsevier, Amsterdam, 1984) vol. 3B.
2) N. Sheppard: Annu. Rev. Phys. Chem. 39, 589 (1988).
3) J.A. Rodriguez and D.W. Goodman: Surf. Sci. Rep. 14,1 (1991).
4) P.S. Cremer, X. Su, Y.R. Shen and G.A. Somorjai: J. Am. Chem. Soc. 118, 2942 (1996).
5) P.S. Cremer, X. Su, Y.R. Shen and G.A. Somorjai: J. Phys. Chem. 100, 16302 (1996).
6) M.B. Hugenschmidt, P. Dolle, J. Jupille and A. Cassuto: J. Vac. Sci. Technol. A 7, 3312 (1989).
7) G.A. Somorjai, M.A. Van Hove and B.E. Bent: J. Phys. Chem. 92, 973 (1988).
8) H. Steininger, H. Ibach and S. Lehwald: Surf. Sci. 117, 685 (1982).
9) L.L. Kesmodel, L.H. Dubois and G.A. Somorjai: J. Chem. Phys. 70, 2180 (1979).
10) F. Zaera: J. Phys. Chem. 94, 5090 (1990), and references therein.
11) T.A. Land, T. Michely, R.J. Behm, J.C. Hemminger and G. Comsa: J. Chem. Phys. 97, 6774 (1992), and references therein.
12) A. Cassuto, M. Mane, M. Hugenschmidt, P. Dolle and J. Jupille: Surf. Sci. 237, 63 (1990).
13) R.G. Windham, M.E. Bartram and B.E. Koel: J. Phys. Chem. 92, 2862 (1988).
14) X. -L. Zhou, X. -Y. Zhu and J. M. White: Surf. Sci. 193, 387 (1988).
15) G. McDougall, H. Yates: Spec. Publ. R. Soc. Chem. 114, 109 (1992).
16) J. Kubota, S. Ichihara, J.N. Kondo, K. Domen and C. Hirose: Langmuir 12, 1926 (1996).
17) J. Kubota, S. Ichihara, J.N. Kondo, K. Domen and C. Hirose: Surf. Sci. 357/358, 634 (1996).
18) F.M. Hoffmann: Surf. Sci. Rep. 3,107 (1983).
19) Y.J. Chabal: Surf. Sci. Rep. 8, 211 (1988).
20) H. Hoffmann, P.R. Griffiths and F. Zaera: Surf. Sci. 262,141 (1992).
21) J. Fan and M. Trenary: Langmuir 10, 3649 (1994)
22) K. Griffiths, W.N. Lennard, IV. Mitchell, P.R. Norton, G. Pirug and H.P. Bonzel: Surf. Sci. 284, L389 (1993).
23) R. Döll, C.A. Gerken, M.A. Van Hove and G.A. Somorjai: Surf. Sci. 374, 151 (1997).
24) E.A. Caeter and B.E. Koel: Surf. Sci. 226, 339 (1990).
25) M. Salmerón and G.A. Somorjai: J. Phys. Chem. 86, 341 (1982).
26) N.R. Avery: Langmuir 4, 445 (1988).
27) E.A. Carter and W.A. Goddard, III: Surf. Sci. 209, 243 (1989).
28) I.J. Malik, M.E. Brubaker, S.B. Mohsin and M. Trenary: J. Chem. Phys. 87, 5554 (1987).
29) I.A. Ransley, L.M. Ilharco, J.E. Bateman, B.H. Sakakini, J.C. Vickerman and M.A. Chesters: Surf. Sci. 298, 187 (1993).
Right : 1) J.C. Bertolini and J. Massardier: “The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis”, ed. by D.A. King and D.P. Woodruff (Elsevier, Amsterdam, 1984) vol. 3B.
2) N. Sheppard: Annu. Rev. Phys. Chem. 39, 589 (1988).
3) J.A. Rodriguez and D.W. Goodman: Surf. Sci. Rep. 14,1 (1991).
4) P.S. Cremer, X. Su, Y.R. Shen and G.A. Somorjai: J. Am. Chem. Soc. 118, 2942 (1996).
5) P.S. Cremer, X. Su, Y.R. Shen and G.A. Somorjai: J. Phys. Chem. 100, 16302 (1996).
6) M.B. Hugenschmidt, P. Dolle, J. Jupille and A. Cassuto: J. Vac. Sci. Technol. A 7, 3312 (1989).
7) G.A. Somorjai, M.A. Van Hove and B.E. Bent: J. Phys. Chem. 92, 973 (1988).
8) H. Steininger, H. Ibach and S. Lehwald: Surf. Sci. 117, 685 (1982).
9) L.L. Kesmodel, L.H. Dubois and G.A. Somorjai: J. Chem. Phys. 70, 2180 (1979).
10) F. Zaera: J. Phys. Chem. 94, 5090 (1990), and references therein.
11) T.A. Land, T. Michely, R.J. Behm, J.C. Hemminger and G. Comsa: J. Chem. Phys. 97, 6774 (1992), and references therein.
12) A. Cassuto, M. Mane, M. Hugenschmidt, P. Dolle and J. Jupille: Surf. Sci. 237, 63 (1990).
13) R.G. Windham, M.E. Bartram and B.E. Koel: J. Phys. Chem. 92, 2862 (1988).
14) X. -L. Zhou, X. -Y. Zhu and J. M. White: Surf. Sci. 193, 387 (1988).
15) G. McDougall, H. Yates: Spec. Publ. R. Soc. Chem. 114, 109 (1992).
16) J. Kubota, S. Ichihara, J.N. Kondo, K. Domen and C. Hirose: Langmuir 12, 1926 (1996).
17) J. Kubota, S. Ichihara, J.N. Kondo, K. Domen and C. Hirose: Surf. Sci. 357/358, 634 (1996).
18) F.M. Hoffmann: Surf. Sci. Rep. 3,107 (1983).
19) Y.J. Chabal: Surf. Sci. Rep. 8, 211 (1988).
20) H. Hoffmann, P.R. Griffiths and F. Zaera: Surf. Sci. 262,141 (1992).
21) J. Fan and M. Trenary: Langmuir 10, 3649 (1994)
22) K. Griffiths, W.N. Lennard, IV. Mitchell, P.R. Norton, G. Pirug and H.P. Bonzel: Surf. Sci. 284, L389 (1993).
23) R. Döll, C.A. Gerken, M.A. Van Hove and G.A. Somorjai: Surf. Sci. 374, 151 (1997).
24) E.A. Caeter and B.E. Koel: Surf. Sci. 226, 339 (1990).
25) M. Salmerón and G.A. Somorjai: J. Phys. Chem. 86, 341 (1982).
26) N.R. Avery: Langmuir 4, 445 (1988).
27) E.A. Carter and W.A. Goddard, III: Surf. Sci. 209, 243 (1989).
28) I.J. Malik, M.E. Brubaker, S.B. Mohsin and M. Trenary: J. Chem. Phys. 87, 5554 (1987).
29) I.A. Ransley, L.M. Ilharco, J.E. Bateman, B.H. Sakakini, J.C. Vickerman and M.A. Chesters: Surf. Sci. 298, 187 (1993).
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