Hyomen Kagaku
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
RHEED-AES Observation of Sb Desorption on a Single-Domain Si(001)2×1 Surface
Ki-Seon KIMYuji TAKAKUWATadashi ABUKAWAShozo KONO
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1997 Volume 18 Issue 8 Pages 501-505

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Abstract

Sb desorption on a single-domain Si(001)2×1 surface has been studied using grazing-incidence reflection high energy electron diffraction and Auger electron spectroscopy (RHEED-AES). From the time evolution of Sb coverage, θSb, during Sb desorption as monitored from Sb MNN Auger spectra, we have found that the Sb desorption kinetics are divided into two coverage regions; (I) 1 ML>θSb>0.3 ML and (II) 0.3 ML>θSb>0 ML. It was also found that the Sb desorption is a first-order reaction in each coverage region with activation energies of (I) 3.61 eV and (II) 3.63 eV and pre-exponential factors of desorption coefficient of (I) 2.9×1015 S-1 and (II) 5.0×1015 S-1. This difference in pre-exponential factor is explained in term of the change in the morphology and structure of Sb layer as monitored by RHEED.

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© The Surface Science Society of Japan
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