表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
ゼオライト膜の合成と応用
水上 富士夫
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ジャーナル フリー

1998 年 19 巻 10 号 p. 658-664

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Zeolite membranes were classified into four types, that is, self-supporting membrane, supported membrane, oriented self-supporting membrane, and disk membrane. Preparation, properties and applications of these membranes are described. Self-supporting membranes are obtained by using Teflon and cellulose as the substrates, but they are fragile. Supporting membranes can be prepared by both traditional hydrothermal synthesis and solid dry-conversion via vaporphase transport, and they have enough mechanical strength to be used for separation by pervaporation. An oriented self-supporting membrane can be obtained by using mercury surface as the substrate, which is transparent and shows molecular sieving effect for permeation of hexane isomers. A disk membrane can be prepared by heating a shaped mixture of silica or aluminosilicate containing an organic amine in a sealed system and used for a catalytic membrane.

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