表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
Si(111)表面上の孤立したシリコン島状結晶の緩和過程
一宮 彪彦林 和彦
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1999 年 20 巻 12 号 p. 865-871

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Thermal relaxation of isolated single silicon two dimensional (2D) islands, 2D vacancy islands and pyramid type islands, produced on the Si(111)(7×7) surface by using a tip of a scanning tunneling microscope are observed by temperature variable scanning tunneling microscopy. Thermal decay rates of silicon islands are measured at various substrate temperatures of 650 K-850 K. Effects of the probe tip on the rates are measured and reduced rates are determined without the tip effects. The sizes of islands depend on time with a function form of (t0-t)α. For single bilayer islands, α was 1 without the tip effects and 2/3 with the tip effects. From these results, we conclude that the intrinsic decay process of islands is attachment-detachment limited but is diffusion limited with the tip effect. Activation energies for the intrinsic decay of single 2D islands and 2 D vacancy islands are 1.5 eV and 1.3 eV, respectively. Characteristic (5×5) islands with long life times are found during decay. The (5×5) structure is also observed on pyramid type island surfaces. We discuss the results in terms of two dimensional vapor phase processes.

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© 社団法人 日本表面科学会
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